Beilstein J. Org. Chem.2011,7, 555–564, doi:10.3762/bjoc.7.64
showed good catalytic activities in the asymmetric intramolecular hydroamination reaction to give the corresponding product in moderate ee.
Keywords: chiralmono(N-heterocycliccarbene) complex; Heck–Mizoroki reaction; hydroamination; Suzuki–Miyaura reaction; Introduction
N-heterocyclic carbene (NHC
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Graphical Abstract
Figure 1:
Monodentate NHCs with sterically hindered N-substituents.